The Smoke, Clouds And Radiation Field Project in Brazil (SCAR-B) took place in the Brazilian Amazon and cerrado regions in August-September 1995, as a collaboration between Brazilian and American scientists. SCAR-B, a comprehensive experiment to study biomass burning, emphasized measurements of surface biomass, fires, smoke aerosol and trace gases, clouds, and radiation, their climatic effects, and remote sensing from aircraft and satellites. It included aircraft and ground-based in situ measurements of smoke emission factors, and the compositions, sizes, and optical properties of the smoke particles; studies of the formation of ozone; the transport and evolution of smoke; and smoke interactions with water vapor and clouds. This overview paper introduces SCAR-B and summarizes some of the main results obtained so far: (1) Fires: measurements of the size distribution of fires, using the 50 m resolution MODIS Airborne Simulator, show that most of the fires are small (e.g., 0.005 km2) but the satellite sensors (e.g., AVHRR and MODIS with 1 km resolution) can detect fires in Brazil that are responsible for 60-85% of the burned biomass; (2) Aerosol: smoke particles emitted from fires increase their radius by as much as 60% during their first three days in the atmosphere due to condensation and coagulation, reaching a mass median radius of 0.13-0.17 µm; (3) Radiative forcing: estimates of the globally-averaged direct radiative forcing due to smoke worldwide, based on the properties of smoke measured in SCAR-B (-0.1 to -0.3 W m-2) are smaller than previously modeled due to a lower single scattering albedo (0.8 to 0.9), smaller scattering efficiency (3 m2 g-1 at 550 nm), and low humidification factor; and (4) Effect on clouds: a good relationship was found between cloud condensation nuclei and smoke volume concentrations, thus an increase in the smoke emission is expected to affect cloud properties. In SCAR-B new techniques were developed for deriving the absorption and refractive index of smoke from ground-based remote sensing. Future spaceborne radiometers (e.g., MODIS on the Earth Observing System), simulated on aircraft, proved to be very useful for monitoring smoke properties, surface properties, and the impacts of smoke on radiation and climate.